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Journal Articles

Thermal and mechanical properties of CeO$$_{2}$$

Suzuki, Kiichi; Kato, Masato; Sunaoshi, Takeo*; Uno, Hiroki*; Carvajal-Nunez, U.*; Nelson, A. T.*; McClellan, K. J.*

Journal of the American Ceramic Society, 102(4), p.1994 - 2008, 2019/04

 Times Cited Count:36 Percentile:90.42(Materials Science, Ceramics)

The fundamental properties of CeO$$_{2}$$ were assessed using a range of experimental techniques. The oxygen potential of CeO$$_{2}$$ was measured by the thermogravimetric technique, and a numerical fit for the oxygen potential of CeO$$_{2}$$ is derived based on defect chemistry. Mechanical properties of CeO$$_{2}$$ were obtained using sound velocity measurement, resonant ultrasound spectroscopy and nanoindentation. The obtained mechanical properties of CeO$$_{2}$$ are then used to evaluate the Debye temperature and Gruneisen constant. The heat capacity and thermal conductivity of CeO$$_{2}$$ were also calculated using the Debye temperature and the Gruneisen constant. Finally, the thermal conductivity was calculated based upon laser flash analysis measurements. This result demonstrates that the thermal conductivity has strong dependence upon material purity.

Journal Articles

Mechanical and thermal properties of (U,Pu)O$$_{2-x}$$

Hirooka, Shun; Kato, Masato

Proceedings of International Conference on Fast Reactors and Related Fuel Cycles; Next Generation Nuclear Systems for Sustainable Development (FR-17) (USB Flash Drive), 6 Pages, 2017/06

Young's modulus of MOX pellets was evaluated by measuring the sound velocities of longitudinal and transverse waves in the pellets as functions of porosity, oxygen-to-metal ratio (O/M) and plutonium content. The results showed that porosity was the most important factor that 20% of the porosity decreased Young's modulus by neatly 100 GPa while O/M and plutonium content could change the Young's modulus by ~20 GPa. From the measured sound velocities, temperature dependence on Young's modulus and specific heat capacity were calculated on the Debye model by leveraging the thermal expansion data. The temperature dependence that Young's modulus decreases with increasing temperature is in good agreement with literature data. The specific heat capacity also agrees with that of calculated value by Kopp's method, taken the Schottky term and the excited term into account.

Journal Articles

Novel pressure phase diagram of heavy fermion superconductor CePt$$_{3}$$Si investigated by ac calorimetry

Tateiwa, Naoyuki; Haga, Yoshinori; Matsuda, Tatsuma; Ikeda, Shugo; Yasuda, Takashi*; Takeuchi, Tetsuya*; Settai, Rikio*; Onuki, Yoshichika

Journal of the Physical Society of Japan, 74(7), p.1903 - 1906, 2005/07

 Times Cited Count:71 Percentile:89.02(Physics, Multidisciplinary)

The pressure dependences of the antiferromagnetic and superconducting transition temperatures have been investigated by ac heat capacity measurement under high pressures for the heavy-fermion superconductor CePt$$_3$$Si without inversion symmetry in the tetragonal structure. The N$'e$el temperature $$T_{rm N}$$ = 2.2 K decreases with increasing pressure and becomes zero at the critical pressure $$P_{rm AF}$$ $$simeq$$ 0.6 GPa. On the other hand, the superconducting phase exists in a wider pressure region from ambient pressure to about 1.5 GPa. The pressure phase diagram of CePt$$_3$$Si is thus very unique and has never been reported before for other heavy fermion superconductors.

Journal Articles

Heat capacity of neptunium mononitride

Nakajima, Kunihisa; Arai, Yasuo

Journal of Nuclear Science and Technology, 39(Suppl.3), p.620 - 623, 2002/11

no abstracts in English

Journal Articles

Heat capacity measurements on unirradiated and irradiated fuel pellets

Amaya, M.*; Une, Katsumi*; Minato, Kazuo

Journal of Nuclear Materials, 294(1-2), p.1 - 7, 2001/04

 Times Cited Count:12 Percentile:64.73(Materials Science, Multidisciplinary)

no abstracts in English

JAEA Reports

Comparison of heat capacity and thermal time constant between BWR fuel and simulated heater rod

Iguchi, Tadashi

JAERI-Research 2000-050, 107 Pages, 2000/09

JAERI-Research-2000-050.pdf:4.29MB

no abstracts in English

Journal Articles

Characterization of technetium-ruthenium alloys for transmutation of technetium metal

Shirasu, Yoshiro; Minato, Kazuo

Proc. of the Int. Conf. on Future Nuclear Systems (GLOBAL'99)(CD-ROM), 7 Pages, 1999/00

no abstracts in English

Journal Articles

Properties of technetium and technetium-ruthenium alloys for transmutation of technetium

Minato, Kazuo; Shirasu, Yoshiro

Proceedings of 2nd Japanese-Russian Seminar on Technetium, p.77 - 78, 1999/00

no abstracts in English

Journal Articles

Thermal conductivity of technetium

Minato, Kazuo; Serizawa, Hiroyuki; Fukuda, Kosaku

Journal of Alloys and Compounds, 267, p.274 - 278, 1998/00

 Times Cited Count:7 Percentile:49.92(Chemistry, Physical)

no abstracts in English

Journal Articles

Thermodynamic study of UO$$_{2}$$$$_{+}$$$$_{x}$$ by solid state EMF technique

Nakamura, Akio; Fujino, Takeo

Journal of Nuclear Materials, 149(1), p.80 - 100, 1987/01

 Times Cited Count:44 Percentile:95.53(Materials Science, Multidisciplinary)

no abstracts in English

Journal Articles

Phase transition in K$$_{2}$$SO$$_{4}$$ at 56K

; *; *

Ferroelectrics Letters, 44, p.71 - 75, 1982/00

 Times Cited Count:12 Percentile:53.58(Physics, Condensed Matter)

no abstracts in English

Journal Articles

Isoperibol type,Laser-Flash calorimeter for precise heat-capacity measurement

*; *; ; *

Netsu Sokutei, 7(4), p.107 - 111, 1980/00

no abstracts in English

Oral presentation

Thermophyisical properties of (U,Ce)O$$_{2pm x}$$

White, J.*; Hirooka, Shun; Murakami, Tatsutoshi; Nelson, A.*; McClellan, K.*; Kato, Masato

no journal, , 

Use of CeO$$_{2}$$ as a surrogate to better understand the behavior of MOX fuels requires a fundamental investigation of the thermophysical properties to assess the appropriate use. The challenge in performing thermophysical property measurements on oxygen non-toichiometric MOX is in handling the kinetics at elevated temperatures and also in determining a reference state from which to measure the oxygen:metal ratio (O:M). This study integrated the use of identical gas handling systems installed on a thermogravimetric analyzer and the property measurement system (differential scanning calorimeter and laser flash analyzer) to control the partial pressure of oxygen, PO$$_{2}$$, between the system and maintain stoichiometry from ambient temperature to 1200$$^{circ}$$C.

Oral presentation

Measurement of high temperature heat capacity and thermal diffusivity of (U,Pu)O$$_{2}$$ as a function of Pu content

Hirooka, Shun; Matsumoto, Taku; Morimoto, Kyoichi; Ogasawara, Masahiro*; Murakami, Tatsutoshi; Kato, Masato

no journal, , 

no abstracts in English

14 (Records 1-14 displayed on this page)
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